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Showing posts sorted by relevance for query methanol from bagasse,maui. Sort by date Show all posts
Showing posts sorted by relevance for query methanol from bagasse,maui. Sort by date Show all posts

Wednesday, January 16, 2019

MY LIFE in BIOMASS and BIOFUELS

I was planning a biomass career while at Stanford, for I applied for and got a summer job after my junior year with C. Brewer, then the oldest company in Hawaii.  I was placed to stay in a room at the Boys Club in Hilo and I was assigned to a sugar analysis laboratory.  In my front yard was the ballpark the Hilo little league team used.  They made it all the way to Williamsport that Summer of '61.

Upon graduation in 1962, most of my close friends joined the first full-year of the Peace Corps.  They were to get paid $99/month to spend two years in some God-forsaken location, literally, like French Guinea and Cameroon.  My "sacrifice" to toil for the Hutchinson sugar company in Naalehu on the Big Island as a biomass process engineer paid $500/month, and, more importantly, changed my whole life.  I bought my first car, a Triumph TR-3.  I married Pearl, who was a nurse in the next town, Pahala.  We later also spent some time in Kilauea, Kauai, where I met an elderly gentleman who knew my grandfather, leading to The Search for Kenjiro's Grandmothers nearly half a century later.

I learned how difficult it was to grow cane, harvest it and process the crop in a factory.  No one tells you this, but there are swarms of flying cockroaches in this environment.  Then when you burn a canefield, hordes of rats escape.  Hawaii came to be, that is, our ethnic balance, because of sugar.  I probably contributed to the decline of the business in my six years with C. Brewer, for we now have no sugar industry and no C. Brewer.

In 1964 Pearl and I returned to Naalehu, but after a short while felt it was time to try graduate school.  Manager of Hutchinson, Bill Baldwin (right--a decade later we shared the same office working for Senator Spark Matsunaga in DC), somehow talked the upper administration into paying my salary while in school, but only if I went to Louisiana State University, for they had the only sugar program in the world.  I actually got a full fellowship from LSU too, so life was swell.  This eventually led to a PhD in biochemical engineering and a job at the University of Hawaii College of Engineering (UHCOE).

My first project at the UHCOE was as a reservoir engineer for the Hawaii Geothermal Project.  Geothermal energy will be the focus next Wednesday.

However, my next few assignments, all in the 1970's, dealt with biomass and biofuels.  First, I built a raceway (I'm here at an upgraded facility) to grow microalgae, linked to the emission from a small powerplant.  The purpose was two-fold:  grow algae which could be processed into a biofuel and utilize the carbon dioxide to reduce climate warming.  In the mid-1970's very few had any inkling of this potentially serious environmental problem.  There was uneasiness about fluorocarbons affecting the ozone layer and air pollution, but nothing yet about the dangers of carbon dioxide.

A second project was a U.S. Department of Energy grant to determine what was the best biofuel to develop from biomass.  We looked closely at ethanol, for that is where the USDOE was determined to go, as influenced by the Farm Lobby.  We thought that the gasification and catalysis into bio-methanol was the optimal direction, especially if the direct methanol fuel cell could be perfected for transport applications.

Armed with this special piece of information, in the 1980's I directed an effort launched by the Pacific International Center for High Technology Research (PICHTR) to gain funding to build a bio-methanol facility at a sugar factory on Maui, using bagasse as the biomass source.  We secured $25 million, mostly from the Department of Energy, and I returned to the UH to focus on the Blue Revolution.  For a variety of reasons, not one drop of methanol was produced.  We probably till today (and maybe tomorrow) killed future interest in this pathway.

What a shame, for first, that biofuel could be directly combusted in a car engine.  Many racing drivers prefer methanol over other liquid fuels.  The development of the direct methanol fuel cell could serve as the bridge to a hydrogen economy.  If only the world went our way, but the Farm Lobby conned the nation and world.  Four years ago decision-makers finally came to a consensus that ethanol from corn was a terrible idea.

When I wrote my SIMPLE SOLUTIONS for Planet Earth a decade ago, the world was using 400 Quads of energy.  Today, this total is over 600 Q.  Here is another rather depressing bit of news:

The U.S. Energy Information Administration (EIA) estimates that, in 2015, around 12% of world marketed (bought and sold) energy consumption came from renewable sources (biomass, geothermal, hydropower, solar, and wind).[1] EIA projections suggest that this will increase to 17% by 2040.

In other words, fossil fuels and nuclear fission will continue to provide 83% of our energy usage more than two decades from today.

Biomass has historically supplied a significant share of the world energy consumption, for the period before the Civil war, wood was by far the dominant fuel of choice. That thin gold sliver in the pie chart below?  All the wind, solar, geothermal and other clean energy supplied.  So much hoopla, but so tiny.  Note how large the pie piece is for biomass.

The most promising future biomass is marine algae. We will re-visit this option in Chapter 4 on the Blue Revolution, but to quote a colleague, Jaw Kai Wang, from personal notes (gallons oil / year / acre):

o Corn 18
o Soybean 48
o Sunflower 102
o Palm oil 635
o Marine algae 10,000
What about trees and forests?   Sure, they consume carbon dioxide and release oxygen.  However, keep in mind that they don't suck up any carbon dioxide when there is no sun.  In fact, plants then release carbon dioxide, and worse, they also give off methane, which is 25 times worse than carbon dioxide as a greenhouse gas.  And the part no one really says much:  trees eventually die, and give back the carbon dioxide into the atmosphere, plus, depending on environmental conditions, release even more methane, so the net balance to global warming is contributory.  There is that bridge of time you gain when trees are growing, but there is a limit to that lifetime.  Thus, there is some concern about the relative goodness of trees.

More recently, Honua Ola, which wants to burn biomass to generate 21.5 MW on the Big Island, has again run into problems.  There is a NIMBY (not in my back yard) syndrome that is plaguing Hawaii, and and world, too.  We last week saw this in wind power.  But Governor David Ige is supportive and they recently hired as president Warren Lee, former president of HELCO.

There is some ethanol from cellulosic biomass R&D perking along in the U.S. and world, but biofuels from biomass will not become competitive until oil reaches a price far north of $100/barrel.  Research dawdles along on micro direct methanol fuel cells, for portable electronic applications.  I still think that the direct methanol fuel cell is the right path to the future of ground transportation, not batteries.

What about the future of sustainable aviation?  Read my HuffPo.  Our Department of Defense reached out too far during the Obama years, so has pulled back.  The economics were horrible.  Some R&D is continuing.

What about hydrogen?  Read:

     THE FUTURE OF CARBON-FREE NEXT GENERATION AVIATION (Part 3:  Hydrogen Planes)

The latest seems to be from Singapore.  Only a four passenger Element One using a hydrogen fuel cell.

Okay, so what about microalgae, for if Jaw Kai Wang is right, this should just be a matter of time.  Well, as difficult as the economics are for simple biomass to biofuels, the complexity expands for microorganisms.  Read pages 49-68 of Renewable and Sustainable Energy Reviews, Volume 94, October 2018.  This option, too, is awaiting the exponential rise of oil prices.

After I retired, I led another team about a decade ago in a five-year study to evaluate for the Department of Energy how competitive marine algae could be for biofuels production.  After five years of analysis, we chose not to publish, for the cost was prohibitive.  While the more optimistic thought that this technology could be commercialized if oil reached $125/bbl, a couple of respected pessimists thought something over $200/bbl would need to be the target.  Oil prices have been depressed now for nearly seven years.  Last month petroleum was down below $43/barrel, and is today at around $52/barrel (note the right column).

So what about biomass?  It is a green source well-utilized today around the world, especially in undeveloped nations for cooking and such.  If, somehow, progressive minds with good financing can develop an effective direct methanol fuel cell, and, in parallel, an efficient catalyst can be found to gasify methane into methanol, I see this pathway as the bridge to an eventual hydrogen economy for ground transport.  My discussions with Toyota and Honda representatives tell me that they have decided to go directly to hydrogen, which, I think, is premature.

But the overwhelming factor is the price of oil, which is totally unpredictable.  Look at those spikes in the above graph.  Yet, if the Chicago Mercantile Exchange is right, you can look forward to $54.46/barrel oil...in December of 2027!


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Wednesday, August 19, 2020

IF I WERE TO DESIGN A BLUE REVOLUTION HEADQUARTERS

From Worldometer,  COVID-19 new deaths:

           DAY USA   WORLD   Brazil      India   South Africa
June      9     1093    4732        1185      246         82
July       1       676    4857        1057      438         92
             5       251    3572          535       421       173
             7       993    5504        1312       479       192
           12       380    4118          659       500       108
           14       935    5414        1341       586       174
           15     1001    5760        1261       614       107
           19       412    4606          715       675         85
           21     1119    5669        1346       671        195
           22     1205    7128        1293     1120        572
           26       450    4307         556       715        114
           28    1266     5589         955       776        190
Aug      1    1462     6429       1191       765        193
            2     1123     5601       1048       852        148
            3       467     4430         514       514        213
            5     1362     6292       1394       849        345
          10       534     4813         593     1013        198
          11       569     4575         721       887        213
          12     1504     6556       1242       835        130
          13     1386     6816       1164       950        129
          14     1284     6653       1301     1006        260
          15     1071     5410         726       950        121
          16       522     4525         582       961        162
          17       589     4289         775       880        143
          18     1358     6312        1365    1089        282

Summary:  What the heck happened?  Every one of these new deaths figures is higher than those June 9 numbers at the top!  Just when many thought the pandemic was going away, we get this re-shock.  The same time period in the future will take us just about to November 3, the date of the presidential election.

The Democratic National Convention continues tonight with Kamala Harris, Barack Obama, Hillary Clinton, Elizabeth Warren, Nancy Pelosi and others, with the theme being A More Perfect Union.  Tonight's moderator will be Kerry Washington.

Ruth Marcus of The Washington Post had an op-ed today about two Obama speeches.  The truly memorable one was at this convention in 2004 when Barack Obama made what might have been the best in history.  Watch him if you have 16 minutes to spare.  Then, of course, Monday night, when Michelle went high...for Trump's jugular.
Incidentally, ever wonder why, in this pandemic with a rotten economy, stocks are doing relatively well?  The S&P 500 hit an all-time high yesterday:
  • The market is not geared for today, but 12 to 18 months in the future, 
  • a vaccine for COVID-19 looks promising, 
  • the Federal Reserve keeps saving the economy, 
  • and investors expect some further help from the Congress.
Now on to further thoughts of the Blue Revolution.  In my junior year at Stanford I gained a vision of designing a tall skyscraper that rotated.  So I went to the Architecture Department and inquired about switching majors.  To meet the requirements I had to spend an extra year on campus.  So I passed and remained in Chemical Engineering.

Upon graduating, as I had taken as many art courses as those in my field, I gave some serious thought to going to Sophia University in Tokyo to study art.  But then my close friends all joined the first full year of the Peace Corps, and were preparing to head towards developing countries in the Pacific Islands and African continent, for $99/month.  So I had to reconsider.  With social conscience in mind too, I thought I would return home and save the sugar industry.  I got $500/month.  Doesn't sound like much, but this value in 2020 dollars ranges from $3,300 to $17,700, depending on what economic commodity you use as a comparison.  Further, the job provided a trainee cottage, then when I was hired by a company, as I was by the Hutchinson Sugar Company in Naalehu on the Big Island, a free home and jeep.  Most importantly, it turned out, they are the ones who sent me to graduate school to learn sugar engineering at LSU.

However, with their permission, I chose to stay on to gain a PhD in biochemical engineering, and owed them something when I returned, for they had paid my full salary during my first year of school.  Basically, all they asked me to do one summer was write an environmental report for their factories.  However, as a professor of engineering I went out of my way to look out for their future, and initiated a biomass program to convert sugar waste into biofuels.

This led to a $25 million project at HC&S on Maui in the early 1990's to produce biomethanol (same as methanol) from bagasse.  My dream was to use this fuel to power a fuel cell for transportation, as methanol is the ONLY LIQUID that can be directly processed by a fuel cell.  Today, hydrogen is mostly used, but this gas is very expensive to produce.

Methanol is cheaper than ethanol.  Sure, you can directly combust this liquid in an engine, as is used by drag racers, but a fuel cell is a lot more efficient.  This concept, which you can read in several of my Huffington Post articles, is awaiting development.  The downside is that if you drink even a small quantity of methanol you can go blind and die.  However, who drinks gasoline?    Oh, a second hurdle.  No one has yet developed a direct methanol fuel cell for transportation.  However, when accomplished, the only pollution product are water vapor and carbon dioxide, which is balanced to zero by the carbon dioxide that went into the making of the biomass.


Funny how things have a way of returning, but the recent thought, as reported in The New York Times, is for Hawaii to use biomass, again, to replace fossil fuels.  These biofuels range from ethanol, again, for transport, or jet biofuel for aviation.  I hope they give up on ethanol and go on to methanol (gasification and catalysis is a lot faster than fermentation, reducing equipment requirements), and hasten the development of a direct methanol fuel cell for vehicles.  About air travel, someday the industry will convert to hydrogen jetliners, to be re-fueled from the production of hydrogen using ocean thermal energy conversion (OTEC) at floating cities and industrial parks, with quick-moving lighter than air aircraft picking up and running on hydrogen.  Thus, these future ocean metropolises will connect to the rest of the world through hydrogen-powered aircraft.

All this leads into the purpose of this posting today, which is the shape of the Blue Revolution headquarters.  Very recently I had this amazing dream of being in a super-colossal building that wrapped around a cliff over pounding seas.  In April I posted on Dreaming in Purgatory, where I saw myself walking forever in such a structure.  Picture this design covering the whole wall, but extending horizontally for half a mile, with 50 floors and extending out several hundred yards over the ocean.

So I've been collecting designs from the world-wide web to synthesize into my second dream structure (the first was that rotating skyscraper back in college):



What will this super-colossal building look like?  Don't know yet, but not really practical, yet definitely linked to the Blue Revolution.

Thus, inspired by those above designs, I initiated an effort to visualize the Blue Revolution headquarters.  If the Pacific International Ocean Station will be built in our Exclusive Economic Zone, we will need harbor facilities.  Four years ago, Hawaiian Electric Company closed down their power plant located on the fringe of downtown at Honolulu Harbor.  You know why it was sited here?  Whale oil was unloaded at this dock and used to power the facility.


That would be an excellent site to centralize operations.  Time is of the essence, as discussions are no doubt under way to convert this land into some kind of tourist attraction.  Hawaii Pacific University is right next door, so that too can somehow be incorporated into the operations, as perhaps, an international graduate school for ocean resource development.  They already operate Sea Life Park at Makapuu Point.  The BR building will be about as large as those combined power structures, but when seen from this angle, would look like a giant blue wave.  I googled to see if anything would closely resemble this building, but the best I could find was this colorized BMW design in Copenhagen:


Something closer to Hokusai's The Great Wave of Kanagawa would be more desirable:


Someday soon, I will fuse those two images using photoshop or some other mode of illustration.

As this is Wednesday, science day, let me add one more item.  A couple of days ago the thermometer at Death Valley's Furnace Creek, a place I once visited during the peak of summer, recorded a temperature of 130 F.  Global warming, you say?  Well, maybe not, for in 1913 the temperature there reached 134 F.  Certainly, these are the warmest ever for the USA.  But the World?  Yes, if you accept that 134 F reading, which is generally discredited.  The official planet high was 131 F in Tunisia in 1931, which itself has considerable credibility issues.  Weathermen previously felt that a 129.2 F measurement in Death Valley in 2013 was an accurate official high for Planet Earth.  Thus, someday you will read that the official high ever will be that 130 F reading mentioned above.

Finally, watch another example of Mother Nature's fury:


Hate to end so negatively, so here is one about nature's beauty:


Well, back to fury again, as Hurricane Genevieve is now a Category 4, but should weaken into a 3 has she approaches Baha:


You ever wonder why California never gets a hurricane?  Actually, one hit San Diego in 1858, and even this one might have been a maybe.  Why?  Something called the California current, coming down from Canada, keeps the coastline relatively cold.  Even Oxnard in the peak of summer, with Santa Paula, only 15 miles away at 120F, stays cool in the 60s.  I know, I lived there for three summers.  Oxnard gets foggy in July and August.  This is why citruses bear fruits the year around.

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Wednesday, December 16, 2020

MY GRAND SCIENTIFIC CONTRIBUTIONS TO PLANET EARTH AND HUMANITY

  From Worldometer (new deaths yesterday):

        DAY  USA  WORLD   Brazil    India    South Africa

June     9     1093     4732        1185        246       82
July    22     1205     7128        1293      1120      572
Aug    12     1504     6556        1242       835       130
Sept     9     1208     6222        1136      1168        82
Oct     21     1225     6849          571       703        85
Nov    11     1479     10178        564       550        60
           25     2304    12025         620       518      118
           30     1238       8291        317       482        58
Dec       1     2611     11891         697      500      109
             2     2833     12356         669      498        65
             3     2918     12660        776       570        94
             4     2718     12142        674       509      160
             8     2913    11714         796       404      183 
             9     3265    12342         848       337      142
           10     3107    12932         769       487      173
           11     3031     12401        652       440      205
           14     2976     12635        909       384      210


Summary:  Not getting better.  Here is a graphic from The New York Times this morning showing how terrible the situation is in the USA:


Many of these 
countries have shut-down their countries during this holiday period, and they are nowhere as challenged as the U.S.

If you think you are bummed out with this pandemic, some have it worse:

A PhD in biochemical engineering provides a ticket through portals and pathways not open to most.  Armed with this advantage, you have more leverage to save the world.  Of course, most have more meaningful, personal and limited objectives.  I don't know of anyone who has grander visions for Humanity and Planet Earth than me.  Of course, the more imaginative one gets, the more difficult it is to attain any kind of success.

My original title today was MY GRAND SCIENTIFIC FAILURES.  Then, it occurred to me that unlike an artist who paints to produce a portrait, or a chef who blends ingredients to bake a cake, scientists, and even many engineers, are merely part of a longer-term process.  We do what we can to push the boundaries of knowledge, sometimes actually ending up with a product, but much more frequently taking a concept to a point where someone else takes over.  Being at a university gives you the freedom to explore greater unknowns.  I've mostly experienced what might be labeled as failures, but on further thought, are really seeds of progress.  Mind you, I have had a few minor successes:

I was on the Hawaii Geothermal Project team that in the 1970's developed the 3 MW well that initiated the field in Hawaii.  We actually found the highest bottom-hole temperature at that time, 640 F.  Puna Geothermal Ventures built their operations next to our well, and, unfortunately, got mostly inundated by lava.  However, they sufficiently recovered and are today again producing electricity.  My hope is that they can somehow utilize the wastewater to support new industries, as we once did at Noi'i O Puna.  The potential for the Big Island is 500 MW, which can be exported as electricity through underwater cables or hydrogen.

chaired the American Solar Energy Society Wind Energy Division in the 70's, and went on to help draft and pass the first legislation on wind energy systems for the U.S. Congress in 1980 when I worked in the U.S Senate.  Today, it has become the most successful renewable source to be widely commercialized.  The potential is unlimited when someday off shore wind power plants become competitive.

However, much of what else I tried to develop are in the early stages of development:

  • In the mid-70's I also spent some time at the Lawrence Livermore National Laboratory on laser fusion.  Fusion remains 30 years away for commercialization, at best.
  • Also in this period I led a team from the Hawaii Natural Energy Institute on a Department of Energy-funded project to determine, given biomass, what was the ideal biofuel.  We reported that bioethanol was far superior to ethanol, and that the direct methanol fuel cell was worthy of development to power vehicles.  The Farm Lobby overwhelmed our recommendation with their ethanol from corn option, which was an expensive dud of an option.
  • However, the USDOE gave us one more chance by funding a $25 million methanol from bagasse project on Maui, led by the Pacific International Center for High Technology Research, which was overcome by too many environmental requirements and the fact that oil prices reached an all-time low when we were ready to work with industry in the 1990's.
  • I helped write the original Ocean Thermal Energy Conversion (OTEC) bill in 1979 when I worked for the U.S. Senate.  We projected 10,000 MW by the Year 2000.  Today, this sum is close to zero.
  • I wrote the original hydrogen legislation introduced by Senator Spark Matsunaga.  While the bill became law and created funding for the field, hydrogen today is like fusion.  Wonderful, but not now.

So while my life has been mostly grand failures, whoops, make that visionary adventures, I have nevertheless planted some seeds for the future of Humanity and Planet Earth:

  • Someday, we will receive and interpret alien signals to produce an Encyclopedia Galactica and arrive at a solution to world peace.  We can't seem to do this ourselves.
  • While it might be Cold Fusion or very hot, it's just a matter of time before we mimic what the Sun and all stars do to produce useful energy.
  • I still think the best solution for ground transportation is bioemethanol and the direct methanol fuel cell.
Just after World War II, the first hit in Japan was Ringo no Uta, by Michiko Namiki, having to do with apples.  Soon thereafter came Misora Hibari's first hit song at the age of 12 in 1949, Kappa Boogie Woogie, followed by Kanashiki Kuchibue.  

Ironically my song #11 is Hibari's final, Kawa no Nagare no Yo ni, composed by Akira Mitake.  She released this song in 1989 and soon passed away at the age of 52.  

She is considered to be the most popular singer ever in Japan, and this song is regularly rated as all-time #1 in Japan.  She helped inspire Japan out of World War II with her performances as a young child, and eventually recorded an astounding 1200 songs, selling more than 100 million, appearing in 160 films just from 1949 to 1971.

The Three Tenors singing song #11 in Tokyo in 1996.  Two Tenors plus Dina Ross in Osaka in 1997.   By Teresa Teng of Taiwan.  She returns tomorrow. Here, again, is Hibari Misora's final performance of Kawa no Nagare no Yo ni.

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