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Friday, February 24, 2023

HYDROGEN: Part 3--Our Report to MITI About the Japan Hydrogen Research Program

Today is the first anniversary of the Ukraine War.  I was planning to have a long review today, but decided to skip that because all the news channels have special programs. 

Instead, let me only mention that China has become the peacemaker, calling for a cease-fire and open talks as part of a 12-point proposal to end the conflict.

The plan issued Friday morning by the Foreign Ministry also urges the end of Western sanctions imposed on Russia, measures to ensure nuclear facilities, the establishment of humanitarian corridors for the evacuation of civilians and steps to ensure the export of grain, after disruptions caused global food prices to spike.  (To the left, China's foreign policy chief Wan Yi with Vladimir Putin.)


I wasn't planning to have a three-part hydrogen series, but I yesterday gave a travel talk at 15 Craigside on our Regent Seven Seas cruise from Dubai to Singapore, and remember well another talk I gave in Japan in the 1990's, which was a disaster, but with some redeeming humor.  The topic was hydrogen, and deserves a re-telling.

A professor Yoshida of the chemical engineering department at the University of Tokyo was tasked a quarter century ago by the Ministry of International Trade and Industry (MITI--Economy replaced International today) to select three "experts" from the USA to review the nation's hydrogen research program.

  • James Fleming, dean of engineering at the University of Kentucky.
  • David Block (right), director of the Florida Solar Energy Center.
  • Patrick Takahashi, director of the Hawaii Natural Energy Center.
Block and I were at that time also chair of the Department of Energy's respective National Hydrogen Research Centers on our campuses.

Japan paid for two trips each, so we brought our wives.  All other costs were also covered in the country.

We visited seven research centers, four at universities and three in companies.  I should mention that our countries are different.  In the U.S. the better fundamental research is done at universities, compared to in industry.  Japan is the opposite.  Their university research is maybe too fundamental, and all the useful research is accomplished in companies.  Higher education institutions are mostly valued for the students they graduate.

We had a grand time for a week, going around the country with Professor Yoshida to tour these facilities to conduct the review.  We did not need to submit a final report with our views.  All MITI wanted was a final talk by the three of us at their headquarters in Tokyo.

We first had lunch with sake and beer and showed up late to the auditorium.  Very high tech, in a half-bowl shape with all 100 or so seats filled.
  • Jim had planned to use view graphs, but when the device was turned on, the bulb burned out.  There is also a second bulb that is activated by a switch.  But it too did not work.  There was no other machine available.  So he mumbled on verbally for around 15 minutes.
  • Then came Dave, who brought slides.  They gave him one of those linear holders and told him how to load it.  He did so, but the staff member stumbled and all the slides fell out of the holder.  Remember, the audience was sitting there wondering how incompetent we were.  Rather than meticulously reload, he just talked for a while.
  • I saw all this happening, so I asked for one of those Kodak rotating slide projectors.  I know how to load those and quickly practiced my talk in another room, not really using a screen, but satisfied that this was going to work.  Well, turned out that this device also malfunctioned, for the automatic zoom device kept going in and out of focus, and people began to get seasick.  Me included.  Well, I, too, just verbally gave my report.
MITI was then the epitome of high tech in Japan.  This wasn't our fault, but theirs.  They paid for the trip and never asked us for our written views of what was right and wrong with hydrogen research in Japan.  Yoshida himself was not taking all of this too seriously, for he was the one who was enjoying himself at lunch to cause all of us to walk into a theater into obviously irritated officials.

Later at night, reliving this catastrophe with Yoshida and our wives, we laughed that we all have had our problems giving talks in the past.  Fleming, for example, remembered once in a South American university when he was given a small box plugged into the wall, where you had to individually place a slide.  At one point he saw the alarm on the face of the students, and looked to see in his hand a burning slide.  In short, Yoshida thanked us for our help.

I've given at least a thousand talks around the world, and nothing got close to Fleming's burning slide or the MITI disaster.  And this 15 Craigside presentation yesterday might have been my final performance, for I am getting too old.

Finally, I've noticed that I'm now able to keep my weight at 150 and lower.  Reasons?  A lot of sleep (7-12 hours/night) and a minimum amount of solid carbohydrates.  For example, at dinner last night, in the past I would always have rice.  Note:  Chutoro sashimi on a vegetable salad, burdock fish cake, cream tomato soup, hot sake and cold kombucha....but no rice.

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Thursday, February 23, 2023

ARE THERE VAST NATURAL RESOURCES OF HYDROGEN WE HAVE NOT YET FOUND?

From Worldometer (new  COVID-19 deaths yesterday):

         DAY  USA  WORLD    Brazil    India    South Africa

2020
June     9     1093     4732         1185        246       82
July    22      1205     7128         1293      1120     572
Aug    12      1504     6556        1242        835     130
Sept     9      1208      6222       1136       1168       82
Oct     21      1225      6849         571        703       85
Nov    25       2304    12025        620        518      118
Dec    30       3880    14748       1224       299      465
2021
Jan     14      4142     15512       1151        189     712
Feb      3       4005    14265       1209       107      398
Mar      2       1989     9490        1726       110      194
April     6        906    11787         4211       631       37
May     4        853     13667        3025      3786      59 
June    1        287    10637         2346      3205      95
 July    7         251      8440        1595        817      411
Aug     4         656    10120        1118        532      423 
Sept   22      2228      9326          839        279     124
Oct      6       2102      8255          543       315       59
Nov    3        1436      7830         186        458       23
Dec     1       1633      8475          266        477       28
2022
Jan     7        2025      6729         148         285     140
Feb     2        2990   12012          946        991      175
Mar     2        1778     7756          335         173       28 
Apr     1          439      4056          290          52       12
May    5          225      2404         151            ?        64
June    2         216      1413         130           10        31
July    6           316      1627         335           35       12 
Aug    4           311       2138         258          70         ?
Sep    1          272       1732         174            ?         ?
Oct     6          281       1305         119            9         ?
Nov    3          167         980           16            ?         ?
        25            88         985           71             3        ?  
Dec    3          149       1029         131            3         ?
          8          194       1320         104             6       86
        15          147       1295         124             4         ?
        22          289       1637         165             9         ? 
        28          296       1768         337             2         ?
Jan    4          346       1534         207             ?         ?
         5           220       1611         183             ?         ? 
       12           270       1470         128             ?         ?
       19           225       1775         480             ?         ?
        26          351       1361           92             1         7
Feb    1          221       1261         126             ?         ?
          8          329         999           50             2         ?
        15          211         999         132             1         ?
        22          177       1016         312             1         ?

Effective February 1, 2023, the Coronavirus Tracker has switched from LIVE to Daily Updates. 
As a number of major countries have now transitioned to weekly updates, there is no need anymore for immediate updates throughout the day as soon as a new report is released. On January 29, 2020, Worldometer started tracking the coronavirus, providing the most timely and accurate global statistics to all users and institutions around the world at a time when this was extremely challenging. We thank everyone who participated in this extraordinary collaborative effort.

Reporting countries are switching to weekly trends, which are more accurate than those above daily ones.  So here is another view of new cases on a weekly basis:


         DAY     WORLD          #1                          #2                    #3            
2023     
Feb    22       848,465     Japan 172,960    Taiwan 108,832   USA 105,910

Summary:
  • Cases for past week per million population.
    • World  106
    • #1    Nauru  39,622
    • #2    Niue  20,962
    • #3    Taiwan   4,556
    • #4    Austria  3,844
    • #7    S. Korea  1,445
    • #10  New Zealand  1,195
    • #11  Germany  1,175
    • #12  Samoa  1,014
    • #14  Japan  927
    • #23  Russia  665
    • #32  USA  316
    • #39  Canada  199
    • #42  Australia  170
    • #71  Tonga  56
    • #80  New Caledonia  34
    • Interestingly enough, both Nauru and Niue had no deaths this past week.
    • However, Taiwan led the world in deaths for the week per million population.
  • Deaths for the week.
    • World  5120
    • #1  USA  965
    • #2  Japan  787
    • #3  Brazil  487
  • Deaths for the week per million population.
    • World  0.1
    • #1    Taiwan  17
    • #2    Bermuda  1
    • #3    Barbados  7
    • #4    Japan  6
    • #18  USA  3
    • #27  Brazil  2
    • #29  Australia  2
  • In any case, this pandemic is nearing an end, with relatively few deaths now occurring.
  • So how is China doing?
    • This Worldometer table shows that China has only had around half a million cases since the beginning.  This is in comparison to #1 USA with 105 million and India #2 with 45 million.
    • Worldometer shows only 5272 total deaths, with #1 USA at just over one million total deaths and #2 Brazil at around 700,000 total deaths.
    • However, the World Health Organization shows that  China has had nearly 100 million total cases, just below that of the U.S.....and 119,510 total deaths, with the U.S. at just over a million.
    • This would give China a covid mortality rate of 0.12%, with the U.S. at 1%.  How can the U.S. be 10 times higher?  
      • Maybe has something to do with counting asymptomatic case and/or the effectiveness of vaccinations.  Or erroneous data.
      • The flu mortality rate in the U.S. 2017-8 season was 0.27%, or more than double that China mortality rate.
      • The flu mortality rate in the U.S. 2021-2 season  was only 0.06%.
    • The world seasonal flu death range before the pandemic was from nearly 300,000 to 650,000/year.
      • If only 5,000 covid deaths are now occurring/week, multiplying by 52 would give an current annual COVID-19 deaths number of 260,000, OR LOWER THAN THE SEASONAL FLU DEATHS.
      • Time for the World Health Organization to call an end to this pandemic.
      • Or are we in for a next subvariant wave?
      • WHO reported that China yesterday had 12,194 new cases.  The World yesterday had 76,756, with only Japan, Russia and Taiwan with more new cases than China.  The U.S. had 2052 new cases.  But of course we only have a population a fourth of theirs.  Multiplying by 4 would bring our new cases number closer to them on a per capita basis.
I yesterday posted on Hydrogen (also known as Protium) and Muonium.  Looks like Muonium is not, and will never become, an element.  However, hydrogen, unlike, methane, has not previously been found in underground deposits. 
Much of hydrogen has probably leaked out into outer space:


Even with its protective bubble, Earth is losing enough hydrogen to fill a meter-wide balloon every second. No need to worry-- it'll take a few billion years before we lose all our hydrogen this way, but maybe someday in the distant future someone will look at Earth and ask, just as we do of Mars now, was there ever life on this chunk of rock.


The 17 February 2023 issue of Science, however, focused on Hidden Hydrogen.

  • The story began in 1987 when a well was dug for water in the village of Bourakébougou, Mali
    • At a depth of 354 feet, some gas began to escape.
    • A driller peered into the hole while smoking a cigarette, and the gas exploded in his face.
    • A blue fired burned into their fields, and took a weeks to snuff out.
    • The well was capped.
  • In 2007 Aliou Diallo, chair of Petroma, an oil and gas company, acquired rights to prospect the region surrounding Bourakébougou.
  • In 2012, Diallo recruited Chapman Petroleum to determine what was in the borehole.  It was 98% hydrogen.
  • A few months later, a Ford engine was tuned to burn hydrogen and hooked up to a 300-KW generator, giving the village electricity.
  • Diallo changed his company name to Hydroma.
  • The company described the Malian field in the International Journal of Hydrogen Energy.  I am an honorary board member.
  • In 2019. Natural Hydrogen Energy completed their first hydrogen borehole in Nebraska.  Viacheslav Zgonnik is the CEO.  In 2022 the American Association of Petroleum Geologists formed a natural hydrogen committee.  Says that natural hydrogen has the potential to replace all fossil fuels.
Apparently water-rock reactions deep within the Earth can generate hydrogen, which percolates up and accumulates in underground traps.  A trillion ton?  A U.S. Geological Survey model presented at the October 2022 meeting of the Gelogical Society of American speculates that there is enough natural hydrogen to meet global needs for thousands of years.  Thus, this could well be renewable natural hydrogen.

Interest in this new clean energy resource is quickly growing, but the simple fact is that it is too early to speculated about major commercial opportunities.  However, Eric Gaucher left French oil giant Total because it wasn't moving fast enough on hydrogen.  He believes that the Mali discovery could end up in the history books alongside what happened 163 years ago in Titusville Pennsylvania.  In those days, there were oil seeps in places like Iraq and California, but we were blind to what lay underground.  Then on 27 August of 1859 Edwin Drake struck black gold at only 69 feet.

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Wednesday, February 22, 2023

IS THERE AN ELEMENT LIGHTER THAN HYDROGEN?

  • How can this be?  Hydrogen has just one proton and one electron.
  • Well, Muonium also has an electron....BUT NO PROTON.  There is an antimuon inside, which is lighter than a proton.
  • The reason why you don't see Muonium in the Table of Elements is that it is not an element, for it is energetically impossible for this antimuon to transform into a proton.
  • Thus the answer to the title above is NO.
  • Might also mention Positronium, to be defined next.
Some background.
  • Back to hydrogen, its simplest isotope deuterium has one electron, one proton and one neutron, while tritium has one electron, one proton and two neutrons.  
  • Sorry to keep bringing up these terms, but hydrogen is also known as protium
  • There are 90 naturally-occurring elements on Earth, plus 18 or so other artificial ones.
  • Muonium is artificial.
    • Has one electron.  No proton or neutron.
    • The nucleus is an antimuon, which has a life of only 2.2 microseconds.  
      • Can be produced when cosmic rays collide with hydrogen, leading to a series of preliminary decays to the formation of a muon-antimuon pair.
      • Or, by colliding a positron (an antimatter positively charged version of an electron) with an electron.
      • Symbol:  μ+
    • Muonium was discovered in 1960 by Vernon W. Hughes.....so is nothing new.
    • Has chemical symbol Mu.
    • Weighs 200 times the mass of an electron, but 1/9 the rest mass of a proton.
    • A proton is 1836 times heavier than an electron.
  • To confuse you, there is another substance, called True Muonium, which is a bound state of a muon and an antimuon ((μ+μ− ), but has not yet to be observed experimentally.
  • Another artificial atom is the Positronium, consisting of an antimatter positive electron, or positron, orbited by a normal negative electron.  In a tiny fraction of a second, the positron and electron annihilate one another, yielding high-energy gamma-ray photons.  However, before its destruction, a positronium can combine with ordinary atoms to form a hydride or other simple compounds.
  • Scientists are also studying something called muonium helium.  Or is it muonic helium?  I'm getting confused.

Okay, one more graphic, leaving you no doubt still confused.  If nothing else, don't you feel sorry for those physicists who work in this area of science?

So what is the possible real world value to any of the above?  Best I can determine is that these discoveries are crucial for determining everything else, whatever that might be.  Any practical value?  Sure...maybe.  Concept potentially useful in some future instruments.  Perhaps, one of these light elements will someday be stabilized.  For example, a safer hydrogen for use as fuel for ultra jetliners or zeppelin-like craft.

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Tuesday, February 21, 2023

A RECORD THAT I'LL NEVER BREAK

Nostalgic Tuesday finds me in a travel mood.  First, I'm soon to leave for Sydney to catch a Seabourn cruise to Honolulu.  For sure, I'll break that record, which was 24 drinks from Honolulu to Bangkok.  But the cruise will take 53 days, and my flight from Honolulu to Bangkok was completed in less than 24 hours.  I'm planning another around the world trip next year, but I don't see any legs as long as the one in 2011, which I am resurrecting today.  

  • That photo above was my last view of Kauai, as I was headed on to Tokyo.
  • This was my first flight on a first class around the world trip via Star Alliance:  Today I begin my final ash scattering journey.  I'll be stopping through Bangkok, Tokyo, Zurich, Amsterdam, Stockholm, London, Sao Paulo, Rio, Buenos Aires, Lima, Cuzco, Machu Picchu, Las Vegas, Reno, and San Francisco. 
  • The Honolulu to Bangkok leg included a stop in Tokyo, which now puzzles me a bit, for this type of ticket does not allow you to pass through the same city twice.  Perhaps it's okay if one of them is just a stopover for connection purposes.
  • My first drink was champagne.  You can read the details.
  • The last was a Johnny Walker Blue Label.
  • United first class is junk, Lufthansa is very good and Thai is right up there.  Why?
The Thai Air service was remarkable.  First, while boarding, then, certainly on board, but what followed after we landed was extraordinary.  First they shuttled the first class customers on a kind of golf cart, and the immigration/customs area was at least a mile away.  We were assigned a person to fast track us through the process, and this was so quick that we had to wait five minutes for our bags to arrive. This attendant placed my bag and hand carry on a cart and whisked me through customs without the officials even bothering to look at us.  I exchanged some money while he arranged limousine service to the Sheraton Grande Sukhamvit.  Their international airport is only 15 miles away, but from landing to arrival in my hotel room took less than an hour.  The fact that the driver sped on at 80 MPH was a factor, but I felt relaxed and amazed at all this efficiency.  I have a suite overlooking Benjakip Park, with the Queen Sirikit National Convention Center in the background.

I got to the Sheraton Grand Sukhamvit at around midnight, had a sound sleep, and felt perfectly normal the next morning, which was, actually, surprising.


I posted that experience, and would like to show one comment

Carl Weinberg said...

We finished reading your description of the trip, and we were both drunk when we tried to stand up. You definitely have set bar that will hard to match.

See you in SF

Carl and Gerry


Got to say something about Carl, who, sad to say, passed away last year at the age of 92:

  • Born in Germany and escaped the Holocaust as a stowaway on a boat to Norway.
  • Came to America in 1940, the year I was born.  
  • Was president of Oakland High School, where he met Geraldine Murphy.  
  • Got his BS and MS from Cal Berkeley, and another from Vanderbilt.
  • Spent a career in the Air Force, retiring as a Colonel, then returned to California to run the new R&D department of PG&E.
  • He was indeed a trailblazer in renewable energy.
  • He and Gerry kept returning to stay during summer at Bellows Air Force Base on Oahu.
  • We were all good friends with the same goals.

I watched the first night of the 21st season of American Idol, and was impressed with Tyson Venegas, who got a Platinum ticket.  While his bio says from Canada, I think he is a 17-year old singer from the Philippines.

By the way, America's Got Talent: All Stars, will crown the winner next week Monday, February 27.  The eleven finalists, who performed last night were:   Aidan Bryant, Aidan McCann, Ana-Maria Mărgean, Avery Dixon, Bello Sisters, Detroit Youth Choir, Kodi Lee, Light Balance Kids, Mike E. Winfield, Power Duo, and Tom Ball.  There are no cash prizes, just bragging rights.  I predict the winner will be Kodi Lee.  He is blind and autistic, with Addison's disease.  But a true musical savant.  Among his closest competitors will be Light Balance Kids, because they come from Ukraine, and will have a lot of sympathy votes, and an aerialist, who the judges admired.  Half a dozen of them were quite good and deserve to prevail.


I finally finished my Valentine's prime rib last night, and bought an $80/pound otoro maguro to accompany it.  The Bud Light was supplied by 15 Craigside.
Then I noticed this morning that my Honohono orchid plants were budding.
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Monday, February 20, 2023

THE SPECTACULAR RISE AND FALL OF PHIL SPECTOR

This is one of those Mondays when I couldn't figure out what to say.  Some of you went to work, and found out you had this President's Day off.  Sure, President Joe Biden made an unprecedented visit to Kyiv, and that was noteworthy.  Our 98-year former president, Jimmy Carter, is resting reasonably well.

What else?  The weather is fine in much of the world, especially the USA.  This is also World Day of Social Justice, and Carnival Monday.  Think Mardi Gras.  

13 years ago I walked out of my hotel into downtown Munich and experienced an incredible celebration, called Fasching, which in most of southwest Germany is a kind of a one-day Mardi Gras celebrated today.  People are walking around drinking from full bottles of wine, and many are gaudily dressed.  Everything is tolerated by officials.  I also had one of my Best Lunches that day.

In the U.S. this is National Cherry Pie Day.  Also, National Love Your Pet Day.  Owners are encouraged to pamper them.  And how could you forget:  National Muffin Day.  Those who like blueberry muffins have their own day for them, July 11.  Some states like New York and Minnesota have a state muffin.

Ah, well, good a day as any to bring to focus the life of Harvey Phillip Spector, who is a year older than me.  Well, actually, he passed away in 2021.  So, anyway, in 1958 as a freshman at Stanford I fell in love with To Know Him is to Love Him by the Teddy Bears.  Spent three weeks at #1.  Until fairly recently, I had no idea what they looked like.  Now I know that Phil Spector (on the left in that photo) was a founding member and wrote the song.  He also played the guitar in that video.  My freshman roomie thought Him was God.  It was his father.

About Spector, he was born in the Bronx, moved to Los Angeles as a teenager, had that TKHITLH hit, then worked for Leiber and Stoller, a team which had more than 70 chart hits, including Hound Dog, Yakety Yak and Stand By Me.  Co-wrote with Lieber Spanish Harlem for Ben E. King.  At the age of 21 he started his own record company, the youngest ever at that point, and went on to produce a range of entertainment groups, including Ike & Tina Turner, the Crystals and the Ronettes, whose Be My Baby reached #2.

In 1965 produced  Righteous Brothers' You've Lost That Lovin' Feelin', which rose to #1.   In 1967 he was already showing signs of becoming a recluse, marrying Ronnie Bennett, (in the middle) lead singer of the Ronettes in 1968, and appearing as a drug dealer in Easy Rider the following year.  In her memoir, Bennett alleged that Spector imprisoned her in his California mansion and subject her to years of psychological torment.  He did not allow her to perform.  She finally escaped barefoot in 1972.  At their 1974 divorce settlement, she forfeited everything because Spector had threatened to have her killed if she didn't.

In the 70s he made a kind of comeback by producing the Beatles' Let It Be.  Also John Lennon's Imagine.  He was long known for creating the Wall of Sound, featuring multi-channel layering.  The triple album, Concert for Bangladesh with George Harrison used 44 microphones.

He became unreliable in the 70s from substance abuse and mental problems.  Adding to his misery, in 1974 he was seriously injured when his car crashed in Hollywood, throwing him through the windshield.  He was actually declared dead at the scene.  Received 300 stitches to his face and 4000 to the back of his head.  He later began to wear those outlandish wigs.

Worked erratically, many times carrying a gun, for which he was licensed.  Did in 1981 produce Yoko Ono's Season of Glass shortly after the death of John Lennon. For most of the period from the 80's into the early 2000s was in semi-retirement because he was going bonkers.  Maybe that link to his first song dedicated to his father had made an impression, for his dad had committed suicide when he was 9 years old.


In 2003 he shot actress Lana Clarkson in the mouth in his mansion.  He remained free on $1 million bail, with the murder trial delayed until 2007.  There was a mistrial.  There was a retrial in 2008, was judged guilty in 2009 and sentenced to 19 years in jail.

Was inducted into the Rock and Roll Hall of Fame in 1989, but accepted the honor flanked by three beefy bodyguards, and mumbled a few incoherent words about President George Bush.  Stevie Van Zandt said Spector was a genius irredeemably conflicted.  He paved the way for art rock, and strongly influenced groups like the Beatles and Beach Boys.  Brian Wilson of the Beach Boys said Spector was the single most influential producer.  He makes a milestone whenever he goes into the studio.

Here is his last interview in 2008.  You probably saw photos of him.  Here he is in person.  A lot of his best songs included.  Other highlights:

  -  His role in Easy Rider.

  -  The 2013 film Phil Spector featured Al Pacino and Helen Mirren.  Rotten Tomatoes:  50/32.   

  -  He had #1 records in three decades, won a couple of Grammys and was ranked #2 by one source as the greatest record producer.  

What was wrong with him?  He was treated for bipolar disorder (manic depression), Parkinson's disease and lost the ability to speak while incarcerated.  Said to have died in 2021 of COVID-19.  He would have been eligible for parole in 2024.  

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